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A wildlife biologist is interested in testing the pH of the water in a lake.He obtains a 200.0-mL sample of the water and titrates this sample with a 0.050 M NaOH solution.Neutralization of the lake water requires 40.0 mL of the NaOH solution.Is the lake acidic,basic,or neutral?

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A 25.0-mL sample of 1.00 M NH3 is titrated with 0.15 M HCl.What is the pH of the solution after 15.00 mL of acid have been added to the ammonia solution? [Kb(NH3) = 1.8 × 10-5]


A) 10.26
B) 9.30
C) 9.21
D) 8.30
E) 8.21

F) A) and B)
G) C) and E)

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NaCl is added slowly to a solution that is 0.010 M each in Cu+,Ag+,and Au+.The Ksp for CuCl, AgCl,and AuCl are 1.9 × 10-7,1.8 × 10-10,and 2.0 × 10-13,respectively.Which compound will precipitate first?

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Calculate the pH of the solution resulting from the addition of 10.0 mL of 0.10 M NaOH to 50.0 mL of 0.10 M HCN (Ka = 4.9 × 10-10) solution.


A) 5.15
B) 8.71
C) 5.85
D) 9.91
E) 13.0

F) A) and B)
G) A) and C)

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A(n)___________________ occurs when a compound containing an ion in common with a dissolved substance is added to a solution at equilibrium resulting in a shift of the equilibrium to the left.

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What is the [H3O+] in a buffer that consists of 0.30 M HCOOH and 0.20 M HCOONa? [Ka(HCOOH) = 1.7 × 10-4]


A) 1.1 × 10-4 M
B) 2.6 × 10-4 M
C) 4.3 × 10-4 M
D) 6.7 × 10-5 M
E) 1.7 × 10-4 M

F) A) and C)
G) D) and E)

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The solubility of lead(II) iodide is 0.064 g/100 mL at 20°C.What is the solubility product for lead(II) iodide?


A) 1.1 × 10-8
B) 2.7 × 10-9
C) 1.1 × 10-11
D) 2.7 × 10-12
E) 1.1 × 10-3

F) All of the above
G) B) and C)

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Which may be used to prepare a buffer having a pH of 8.8? Ka = 7 × 10-3 for H3PO4; 8 × 10-8 for H2PO4-; 5 × 10-13 for HP O42-


A) NaH2PO4 only
B) NaH2PO4 and Na2HPO4
C) Na3PO4 and Na2HPO4
D) NaHPO4 and H3PO4
E) H3PO4 and Na3PO4

F) A) and C)
G) B) and C)

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40.0 ml of an acetic acid of unknown concentration is titrated with 0.100 M NaOH.After 20.0 mL of the base solution has been added,the pH in the titration flask is 5.10.What was the concentration of the original acetic acid solution? (Ka(CH3COOH) = 1.8 × 10-5)


A) 0.11 M
B) 0.022 M
C) 0.072 M
D) 0.050 M
E) 0.015 M

F) A) and E)
G) All of the above

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The indicator propyl red has Ka = 3.3 × 10-6.What would be the approximate pH range over which it would change color?


A) 3.5 - 5.5
B) 4.5 - 6.5
C) 5.5 - 7.5
D) 6.5 - 8.5
E) 7.5 - 9.5

F) C) and D)
G) B) and E)

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After the equivalence point,the titration curve of a weak acid is identical to that of a ______ ______.

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Propanoic acid (CH3CH2COOH)has a Ka of 1.34 × 10-5.A 25.00-mL sample of 0.1000 mol • L-1 propanoic acid (in flask)is titrated with 0.1000 mol • L-1 NaOH solution,added from a buret.Carry out the calculations of the quantities indicated below. a.The pH after 0.00 mL of NaOH is added. b.The pH after 15.00 mL of NaOH is added.

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What is the name is used to describe the situation when a compound containing an ion in common with a dissolved substance is added to a solution at equilibrium which shifts the equilibrium?


A) Shift ion
B) Shift reagent
C) Equilibrium ion
D) Common ion effect
E) Ion adduct

F) C) and E)
G) A) and B)

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What is the Henderson-Hasselbach equation?


A) What is the Henderson-Hasselbach equation? A)    B)    C)    D)    E)
B) What is the Henderson-Hasselbach equation? A)    B)    C)    D)    E)
C) What is the Henderson-Hasselbach equation? A)    B)    C)    D)    E)
D) What is the Henderson-Hasselbach equation? A)    B)    C)    D)    E)
E) What is the Henderson-Hasselbach equation? A)    B)    C)    D)    E)

F) C) and E)
G) A) and B)

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Calculate the minimum concentration of Mg2+ that must be added to 0.10 M NaF in order to initiate a precipitate of magnesium fluoride.[Ksp(MgF2) = 6.9 × 10-9] rev: 08_14_2014_QC_52437


A) 1.4 × 107 M
B) 6.9 × 10-9 M
C) 6.9 × 10-8 M
D) 1.7 × 10-7 M
E) 6.9 × 10-7 M

F) B) and E)
G) None of the above

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mL of 0.150 M KI? [Ksp(PbI2) =1.4 × 10-8]


A) 2.2 × 10-2 M
B) 1.5 × 10-7 M
C) 6.2 × 10-7 M
D) 9.3 × 10-8 M
E) 1.4 × 10-8 M

F) C) and E)
G) C) and D)

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pH = pKa + log [conjugate base]/[weak acid] is the ______-______ equation.

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Henderson-...

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For PbCl2 (Ksp = 2.4 × 10-4) ,will a precipitate of PbCl2 form when 0.10 L of 3.0 × 10-2M Pb(NO3) 2 is added to 400 mL of 9.0 × 10-2M NaCl?


A) Yes,because Q > Ksp.
B) No,because Q < Ksp.
C) No,because Q = Ksp.
D) Yes,because Q < Ksp.

E) C) and D)
F) B) and C)

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A CH3COOH/CH3COO- buffer can be produced by adding a strong acid to a solution of CH3COO- ions.

A) True
B) False

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Which results in a buffered solution?


A) A solution containing a strong acid and its conjugate base
B) A solution containing a strong base and its conjugate acid
C) A solution containing a catalyst
D) A solution containing two organic liquids
E) A solution containing a weak acid and its conjugate base

F) C) and E)
G) A) and D)

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